catena-Poly[[(2-{[2-(dimethylammonio)-ethyl]iminomethyl}pyridine-kappa N-2, N')bis-(thiocyanato-kappa N)manganese(II)]-mu-thiocyanato-kappa N-2:S]

被引：0

作者：

Wang, Jun ^{[1
]}

Zhu, Wubiao ^{[1
]}

Li, Jichang ^{[1
]}

机构：

[1] Zhongshan Polytechn, Zhongshan 528404, Guangdong, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 17.4; mean σ(C-C) = 0.005 Å; R factor = 0.043; single-crystal X-ray study; T = 296 K; wR factor = 0.098;

D O I：

10.1107/S1600536812032874

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C10H16N3)](n), the Mn-II atom is coordinated by an N, N'-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N5S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)(2)(C10H16N3)] units, giving rise to helical chains extending along the b axis. The chains are further linked through N-H center dot center dot center dot S hydrogen bonds, leading to a three-dimensional supramolecular network.

引用

页码：M1131 / +

页数：8