COORDINATION CHEMISTRY OF ACTINIDES IN MOLTEN-SALTS

被引：22
|
作者：
BARBANEL, YA
KOLIN, VV
KOTLIN, VP
LUMPOV, AA
机构：
[1] Khlopin Radium Institute, Leningrad
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1990年 / 143卷 / 01期
关键词：
D O I：
10.1007/BF02117559
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The problems of actinide molten salt coordination chemistry are considered in terms of spectroscopic parameters as functions of melt composition and temperature. Parameters connected with energy, intensity and fine structure of 5f-5f transitions have been obtained for molten alkali metal chlorides, fluorides and chloride-fluoride mixtures. The regularities of variation of both actinide-chlorine distances and actinide fluorocomplex stability have been studied.
引用
收藏
页码：167 / 179
页数：13
相关论文
共 50 条
  • [41] MOLTEN-SALTS IN PLUTONIUM RECOVERY
    BOWERSOX, DF
    CHRISTENSEN, DC
    WILLIAMS, JD
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (8B) : C512 - C512
  • [42] IONIC DYNAMICS IN MOLTEN-SALTS
    GASKELL, T
    WOOLFSON, MS
    JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1983, 16 (10): : 1793 - 1798
  • [43] BEHAVIOR OF METALS IN THEIR MOLTEN-SALTS
    EMONS, HH
    CHEMICKE ZVESTI, 1974, 28 (04): : 433 - 446
  • [44] SEMICONDUCTOR BEHAVIOR IN MOLTEN-SALTS
    PHILLIPS, J
    GIBBARD, HF
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (03) : C137 - C137
  • [45] LATENT THERMAL STORAGE USING SODIUM HYDROXIDE-BASED MOLTEN-SALTS - COMPATIBILITY OF MOLTEN-SALTS
    ABE, Y
    TAKAHASHI, Y
    SAKAMOTO, R
    KANARI, K
    TANAKA, K
    KAMIMOTO, M
    OZAWA, T
    KAGAKU KOGAKU RONBUNSHU, 1989, 15 (05) : 977 - 984
  • [46] PYROLYSIS OF SCRAP TIRES IN MOLTEN-SALTS
    LARSEN, JW
    ELASTOMERICS, 1977, 109 (04): : 28 - 28
  • [47] ELECTROLYTIC DEPOSITION FROM MOLTEN-SALTS
    WURM, J
    GALVANOTECHNIK, 1979, 70 (05): : 420 - 429
  • [48] GAS SOLUBILITIES IN MOLTEN-SALTS AND SILICATES
    YOKOKAWA, T
    PURE AND APPLIED CHEMISTRY, 1986, 58 (12) : 1547 - 1552
  • [49] STATISTICAL-THEORIES OF MOLTEN-SALTS
    LARSEN, B
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (08) : C407 - C407
  • [50] ORDERING AND COMPLEXING IN BINARY MOLTEN-SALTS
    SABOUNGI, ML
    RAHMAN, A
    BLANDER, M
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (08) : C370 - C370
12345