COORDINATION CHEMISTRY OF ACTINIDES IN MOLTEN-SALTS

被引：22
|
作者：
BARBANEL, YA
KOLIN, VV
KOTLIN, VP
LUMPOV, AA
机构：
[1] Khlopin Radium Institute, Leningrad
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1990年 / 143卷 / 01期
关键词：
D O I：
10.1007/BF02117559
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The problems of actinide molten salt coordination chemistry are considered in terms of spectroscopic parameters as functions of melt composition and temperature. Parameters connected with energy, intensity and fine structure of 5f-5f transitions have been obtained for molten alkali metal chlorides, fluorides and chloride-fluoride mixtures. The regularities of variation of both actinide-chlorine distances and actinide fluorocomplex stability have been studied.
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页码：167 / 179
页数：13
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