A ROOM-TEMPERATURE METHOD FOR THE PREPARATION OF ULTRATHIN SIOX FILMS FROM LANGMUIR-BLODGETT LAYERS

被引：96
|
作者：
MIRLEY, CL
KOBERSTEIN, JT
机构：
[1] Department of Chemical Engineering, Institute of Materials Science U-136, University of Connecticut, Storrs, Connecticut
来源：
LANGMUIR | 1995年 / 11卷 / 04期
关键词：
D O I：
10.1021/la00004a001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Langmuir-Blodgett films prepared from diacid-terminated poly(dimethylsiloxane) can be transformed to SiOx ultrathin films (t = 14 Angstrom) by exposure to UV-ozone at room temperature and atmospheric pressure. The kinetics of the reaction is followed by grazing-incidence infrared spectroscopy and the film composition is determined by angle-resolved X-ray photoelectron spectroscopy. The results show that UV-ozone treatment oxidizes 90% of the methyl side groups to hydroxyl and bridging oxygen species. This technique represents a novel low temperature route for the preparation of ultrathin SiOx films from polysiloxane starting materials.
引用
收藏
页码：1049 / 1052
页数：4
相关论文
共 50 条
  • [21] POSSIBLE EVIDENCE FOR SUPERCONDUCTING PHENOMENA IN LANGMUIR-BLODGETT HETEROFILMS OBSERVED AT ROOM-TEMPERATURE
    HINO, T
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1991, 30 (3A): : L361 - L363
  • [22] Preparation and characteristics of perfluorodiacetylene Langmuir-Blodgett films
    Terasawa, N
    Hayakawa, Y
    Fukaya, H
    Hayashi, E
    Kato, K
    Fujii, S
    Sawada, H
    Li, KH
    Kyokane, J
    POLYMER, 1998, 39 (24) : 5889 - 5892
  • [23] On the preparation of Langmuir-Blodgett films of pyrrole derivatives
    Bonfiglio, A
    Parodi, MT
    Bianco, B
    Ruggeri, G
    MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC MATERIALS SENSORS AND SYSTEMS, 1998, 5 (3-4): : 223 - 226
  • [24] PREPARATION AND CHARACTERIZATION OF PROTEIN LANGMUIR-BLODGETT FILMS
    OWAKU, K
    SHINOHARA, H
    IKARIYAMA, Y
    AIZAWA, M
    THIN SOLID FILMS, 1989, 180 : 61 - 64
  • [25] Preparation of Langmuir-Blodgett films of soluble polypyrrole
    Dhanabalan, A
    Mello, SV
    Oliveira, ON
    MACROMOLECULES, 1998, 31 (06) : 1827 - 1832
  • [26] MICROSCOPICALLY OBSERVED PREPARATION OF LANGMUIR-BLODGETT FILMS
    LOSCHE, M
    RABE, J
    FISCHER, A
    RUCHA, BU
    KNOLL, W
    MOHWALD, H
    THIN SOLID FILMS, 1984, 117 (04) : 269 - 280
  • [27] A room temperature method for the formation of ultrathin SiOx films.
    Muisener, RJ
    Koberstein, JT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 56 - MACR
  • [28] Preparation of clay/metal complex hybrid films by the Langmuir-Blodgett method
    Yamagishi, A
    Umemura, Y
    Tamura, K
    Inukai, K
    KOBUNSHI RONBUNSHU, 2000, 57 (06) : 311 - 323
  • [29] Preparation of lead titanate thin films using Langmuir-Blodgett method
    Sugai, Hiroshi
    Hoshi, Nobuo
    Iijima, Takashi
    Masumoto, Hiroshi
    Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers, 1998, 37 (9 B): : 5118 - 5122
  • [30] Preparation of lead titanate thin films using Langmuir-Blodgett method
    Sugai, H
    Hoshi, N
    Iijima, T
    Matsumoto, H
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1998, 37 (9B): : 5118 - 5122
12345