A FACILE SYNTHESIS OF BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE AND RELATED DONORS FOR SYNTHETIC METALS

被引：1

作者：

MUELLER, H ^{[1
]}

UEBA, Y ^{[1
]}

机构：

[1] SUMITOMO ELECT IND LTD,R&D GRP,KONOHANA KU,OSAKA 554,JAPAN

来源：

SYNTHETIC METALS | 1995年 / 70卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)02811-C

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Bis(ethylenedithio)tetrathiafulvalene (DEDT-TTF; 4a) and related TTF-based donor molecules (4b-d) were prepared in two steps from thiapendione (I). Basic cleavage of 1 yielded the intermediate 4,5-dimercapto-1,3-dithiol-2-one (2) which provided upon alkylation the corresponding 4,5-alkylenedithio-1,3-dithiol-2-ones (3a-d). Coupling of 3a-d in triethyl phosphite furnished the target molecules: BEDT-TTF, bis(propylenedithio)tetrathiafulvalene (BPDT-TTF; 4b), bis[oxybis(methylenethio)]tetrathiafulvalene (BOBMT-TTF; 4c) and bis[thiobis(methylenethio)]tetrathiafulvalene (BTBMT-TTF; 4d). The electrochemical properties of these compounds are briefly discussed. BOBMT-TTF forms a highly conducting charge transfer complex with TCNQ [conductivity(298 K) = 10 S/cm; compaction sample].

引用

页码：1181 / 1182

页数：2

共 10 条

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