1-(2H-1,3-Benzodioxol-5-yl)ethanone thiosemicarbazone

被引：3
|
作者：
de Oliveira, Adriano Bof [1 ]
de Farias, Renan Lira [1 ]
Naether, Christian [2 ]
Jess, Inke [2 ]
Bresolin, Leandro [3 ]
机构：
[1] Univ Fed Sergipe, Dept Quim, Av Marechal Rondon S-N Campus, BR-49100000 Sao Cristovao, SE, Brazil
[2] Christian Albrechts Univ Kiel, Inst Anorgan Chem, D-24118 Kiel, Germany
[3] Univ Fed Rio Grande, Escola Quim & Alimentos, BR-96201900 Rio Grande, RS, Brazil
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813008398
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C10H11N3O 2S, the 1,3-benzodioxole and hydrazinecarbothioamide fragments are nearly planar [(mean deviations from planarity for non-H atoms of 0.0325 (12) Å and 0.0707 (10) Å, respectively] and subtend a dihedral angle of 29.06 (5)°. In the crystal, molecules are linked by pairs of almost linear N - H⋯S hydrogen bonds, forming inversion dimers. These dimers are additionally connected by weaker and strongly bent N - H⋯S interactions into chains along [101]. There is one additional weak N - H⋯O contact which, if considered as an interaction, leads to the formation of a three-dimensional network.
引用
收藏
页码：O644 / +
页数：8
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