APPLICATION OF SPE (SOLID POLYMER ELECTROLYTE) IN ELECTROOXIDATION OF CINNAMYL ALCOHOL(I)

被引：0

作者：

Chen Zhen ^{[1
]}

机构：

[1] Fujian Normal Univ, Expt Ctr, Fuzhou 350007, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 1993年 / 9卷 / 02期

关键词：

SPE technology; Cation exchange membrane; Solid polymer electrolyte; Cinnamyl alcohol;

D O I：

10.3866/PKU.WHXB19930208

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

SPE (Solid Polymer Electrolyte) composite electrodes were utilized for the selective oxidation of allyl alcohol to aldehyde. In order to enhance the reaction selectivity, manganese dioxide was deposited into the Nafion as a mediator. Cinnamyl alcohol was selectively oxidized to cinnamaldehyde with high current efficiency.

引用

页码：181 / 186

页数：6

共 7 条

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[4] OGUMI Z, 1981, DENKI KAGAKU, V49, P212
[5] APPLICATION OF THE SPE METHOD TO ORGANIC ELECTROCHEMISTRY .6. OXIDATION OF CYCLOHEXANOL TO CYCLOHEXANONE ON PT-SPE IN THE PRESENCE OF IODINE AND IODIDE
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[6] APPLICATION OF THE SOLID POLYMER ELECTROLYTE (SPE) METHOD TO ORGANIC ELECTROCHEMISTRY .3. KOLBE TYPE REACTIONS ON PT-SPE
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[7] APPLICATION OF THE SPE METHOD TO ORGANIC ELECTROCHEMISTRY .10. BEHAVIORS OF THE MANGANESE REDOX COUPLE INCORPORATED IN PT-NAFION AND THEIR MEDIATORY OXIDATION OF CINNAMYL ALCOHOL TO CINNAMALDEHYDE
OGUMI, Z
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[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (12) : 3365 - 3368

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