The Influence of Chemical Oxidation on Surface State and Photoluminescence of Porous Silicon

被引:2
作者
Li Jingjian [1 ]
Diao Peng [1 ]
Cai Shengmin [1 ]
Hou Yongtian [2 ]
Wang Xin [2 ]
Zhang Shulin [2 ]
机构
[1] Peking Univ, Dept Chem, Beijing 100871, Peoples R China
[2] Peking Univ, Dept Phys, Beijing 100871, Peoples R China
关键词
Porous silicon; Fourier transformed infrared transmission spectra; Photoluminescence; Photoluminescence mechanism;
D O I
10.3866/PKU.WHXB19940814
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The changes in photoluminescence and FTIR spectra of porous silicon subjected to oxidation were examined. With the increase of oxidizing duration. the relative amount of the Si-H-2 surface species on PS decreases even though the photoluminescence intensity increases, the result suggests that it isn't SiH2 but Si O and Si-O-Si on the interface of PS play a key role in enhancing the photoluminescence. A complete photoluminescence mechanism should consider the influence of surface state of porous silicon based on the quantum confinement effect model.
引用
收藏
页码:737 / 740
页数:4
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