A SINGULAR SUBSTITUENT EFFECT IN THE NICKEL(0) MEDIATED COCYCLISATION OF OCTA-1,7-DIYNES WITH ALKYNOLS - ONE-STEP SYNTHESIS OF TETRALIN LACTONES FROM ACYCLIC PRECURSORS

被引：24

作者：

BHATARAH, P ^{[1
]}

SMITH, EH ^{[1
]}

机构：

[1] IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,S KENSINGTON,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 05期

关键词：

D O I：

10.1039/c39910000277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Whereas the reaction of simple octa-1,7-diynes is fruitless, those bearing ester groups on the terminal positions react with alkynols in the presence of stoichiometric amounts of a nickel(0) reagent derived from NiCl2(PPh3)2 and Bu(n)Li to give tetralin lactones in moderate to good yields.

引用

页码：277 / 278

页数：2

共 5 条

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[5] ONE-STEP SYNTHESIS OF BENZOCYCLOBUTENES INVOLVING COOLIGOMERIZATION OF LINEAR MONOCETYLENES AND DIACETYLENES CATALYZED BY ETA-5-CYCLOPENTADIENYLCOBALT DICARBONYL
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