THE PREPARATION AND ALLYLATION OF PERFLUOROALLYL CADMIUM AND COPPER REAGENTS

被引：20
作者：
BURTON, DJ
TARUMI, Y
HEINZE, PL
机构：
[1] Department of Chemistry, University of Iowa, Iowa City
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 50卷 / 02期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0022-1139(00)80501-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Perfluoroallyl iodide reacts readily with acid-washed cadmium powder in DMF at 0°C to give the F-allylcadmium reagent. Metathesis of F-allylcadmium with Cu(I)Br at -35° C in DMF gives the F-allylcopper reagent. With zinc powder, perfluoroallyl iodide affords mainly F-1,5-hexadiene. Only a low yield of F-allylzinc was detected. Both F-allylcadmium and F-allylcopper react with allyl bromide to yield 1,1,2,3,3-pentafluoro-1,5-hexadiene. © 1990.
引用
收藏
页码：257 / 263
页数：7
相关论文
共 25 条
123