Crystal structure of bis(acetato-kappa O)bis(pyridine-kappa(2)carboxamide oxime-kappa(2) N, N') cadmium ethanol disolvate

被引:4
作者
Liu, Jiyong [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词
crystal structure; Cd-II complex; acetate; pyridine-2-carboxamide oxime; N-H center dot center dot center dot O hydrogen bonding;
D O I
10.1107/S1600536814017978
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cd(CH3COO)(2)(C6H7N3O)(2)]center dot 2C(2)H(5)OH, the Cd-II atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N, N'-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mononuclear complex molecules are assembled into chains along the c-axis direction via N-H center dot center dot center dot O hydrogen-bonding interactions. These chains are further assembled by OH center dot center dot center dot O hydrogen bonds involving the ethanol solvent molecules into a threedimensional supramolecular structure.
引用
收藏
页码:142 / +
页数:8
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