Crystal structure of bis(acetato-kappa O)bis(pyridine-kappa(2)carboxamide oxime-kappa(2) N, N') cadmium ethanol disolvate

被引：5

作者：

Liu, Jiyong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; Cd-II complex; acetate; pyridine-2-carboxamide oxime; N-H center dot center dot center dot O hydrogen bonding;

D O I：

10.1107/S1600536814017978

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cd(CH3COO)(2)(C6H7N3O)(2)]center dot 2C(2)H(5)OH, the Cd-II atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N, N'-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mononuclear complex molecules are assembled into chains along the c-axis direction via N-H center dot center dot center dot O hydrogen-bonding interactions. These chains are further assembled by OH center dot center dot center dot O hydrogen bonds involving the ethanol solvent molecules into a threedimensional supramolecular structure.

引用

页码：142 / +

页数：8

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