THE TRANSPORT OF AMINO-ACIDS BY 18-CROWN-6 THROUGH LIQUID MEMBRANES

被引:22
作者
MUTIHAC, L
MUTIHAC, R
CONSTANTINESCU, T
LUCA, C
机构
[1] UNIV BUCHAREST,FAC PHYS,POB MG-11,R-76900 BUCHAREST,ROMANIA
[2] UNIV BUCHAREST,FAC CHEM,ANALYT CHEM LAB,BUCHAREST,ROMANIA
[3] ROUMANIAN ACAD,INST PHYS CHEM,R-77208 BUCHAREST,ROMANIA
[4] INST POLYTECH GH GHEORGHIU DEJ,DEPT ANALYT CHEM,BUCHAREST,ROMANIA
来源
JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1994年 / 17卷 / 01期
关键词
AMINO ACID; LIQUID MEMBRANE; 18-CROWN-6; ACTIVE TRANSPORT;
D O I
10.1007/BF00707999
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The possibility of separating in cationic form some alpha-amino acids (L-Methionine, L-Leucine, L-Isoleucine, L-Valine, L-Phenylalanine, L-alpha-Alanine and L-Cysteine) from mixtures in the presence of picrate anion has been investigated by means of active transport assisted by a pH gradient through liquid membranes. 18-Crown-6 in 1,2 dichloroethane has been used as a selective carrier. The effect of stirring rates at different volumes of the membrane, suggests a diffusional rate-limiting process of the amino acid transport.
引用
收藏
页码:45 / 51
页数:7
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