THE TRANSPORT OF AMINO-ACIDS BY 18-CROWN-6 THROUGH LIQUID MEMBRANES

被引:22
作者
MUTIHAC, L
MUTIHAC, R
CONSTANTINESCU, T
LUCA, C
机构
[1] UNIV BUCHAREST,FAC PHYS,POB MG-11,R-76900 BUCHAREST,ROMANIA
[2] UNIV BUCHAREST,FAC CHEM,ANALYT CHEM LAB,BUCHAREST,ROMANIA
[3] ROUMANIAN ACAD,INST PHYS CHEM,R-77208 BUCHAREST,ROMANIA
[4] INST POLYTECH GH GHEORGHIU DEJ,DEPT ANALYT CHEM,BUCHAREST,ROMANIA
来源
JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1994年 / 17卷 / 01期
关键词
AMINO ACID; LIQUID MEMBRANE; 18-CROWN-6; ACTIVE TRANSPORT;
D O I
10.1007/BF00707999
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The possibility of separating in cationic form some alpha-amino acids (L-Methionine, L-Leucine, L-Isoleucine, L-Valine, L-Phenylalanine, L-alpha-Alanine and L-Cysteine) from mixtures in the presence of picrate anion has been investigated by means of active transport assisted by a pH gradient through liquid membranes. 18-Crown-6 in 1,2 dichloroethane has been used as a selective carrier. The effect of stirring rates at different volumes of the membrane, suggests a diffusional rate-limiting process of the amino acid transport.
引用
收藏
页码:45 / 51
页数:7
相关论文
共 50 条
[31]   Systematic study of the transfer of amino acids across the water/1,2-dichloroethane interface facilitated by dibenzo-18-crown-6 [J].
Chen, Y ;
Yuan, Y ;
Zhang, MQ ;
Li, F ;
Sun, P ;
Gao, Z ;
Shao, YH .
SCIENCE IN CHINA SERIES B-CHEMISTRY, 2004, 47 (01) :24-33
[32]   Systematic study of the transfer of amino acids across the water/1,2-dichloroethane interface facilitated by dibenzo-18-crown-6 [J].
CHEN Yong YUAN Yi ZHANG Meiqin LI Fei SUN Peng GAO Zhao SHAO YuanhuaState Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun China ;
College of Chemistry and Molecular Engineering Peking University Beijing China .
Science in China(Series B), 2004, (01) :24-33
[33]   Systematic study of the transfer of amino acids across the water/l,2-dichloroethane interface facilitated by dibenzo-18-crown-6 [J].
Yong Chen ;
Yi Yuan ;
Meiqin Zhang ;
Fei Li ;
Peng Sun ;
Zhao Gao ;
Yuanhua Shao .
Science in China Series B: Chemistry, 2004, 47 :24-33
[34]   THE OPTICAL RESOLUTION OF AMINO-ACIDS BY ULTRAFILTRATION MEMBRANES FIXED WITH PLASMA-POLYMERIZED L-MENTHOL [J].
TONE, S ;
MASAWAKI, T ;
HAMADA, T .
JOURNAL OF MEMBRANE SCIENCE, 1995, 103 (1-2) :57-63
[35]   PREPARATION OF CHARGED POLY(VINYL ALCOHOL) GEL MEMBRANES WITH CONTROLLED LATTICE SIZES AND PERMEABILITY OF AMINO-ACIDS [J].
MIYA, M ;
HAMADA, T ;
SHIOMI, T ;
IMAI, K .
KOBUNSHI RONBUNSHU, 1994, 51 (02) :87-92
[36]   LINEAR POLYSILOXANE WITH DIBENZO-18-CROWN-6 MOIETIES AS LIQUID MEMBRANE CARRIER [J].
龚淑玲 ;
卢雪然 ;
卢先明 ;
陈远荫 .
Chinese Journal of Polymer Science, 1995, (02) :173-179
[37]   LINEAR POLYSILOXANE WITH DIBENZO-18-CROWN-6-MOIETIES AS LIQUID MEMBRANE CARRIER [J].
GONG, SL ;
LU, XR ;
LU, XM ;
CHEN, YY .
CHINESE JOURNAL OF POLYMER SCIENCE, 1995, 13 (02) :173-179
[38]   Correlation aspects in extraction and liquid membrane transport of amino acids with macrocyclic ligands [J].
Mutihac, L ;
Buschmann, HJ ;
Bala, C ;
Mutihac, R .
ANALES DE QUIMICA-INTERNATIONAL EDITION, 1997, 93 (05) :332-336
[39]   Extraction of amino acids with emulsion liquid membranes using industrial surfactants and lecithin as stabilisers [J].
Dzygiel, P ;
Wieczorek, P .
JOURNAL OF MEMBRANE SCIENCE, 2000, 172 (1-2) :223-232
[40]   A Study on Complexation and Transport of Cr(III) Through a Chromogenic Aza Crown Liquid Membrane [J].
Mehta, H. S. ;
Kaur, H. ;
Menon, S. K. .
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2011, 48 (02) :148-154