SURFACE CORRUGATION EFFECTS ON THE ADSORPTION DYNAMICS OF XENON ON PT(110)-(1X2)

被引:20
|
作者
SCHROEDER, S
MCMASTER, MC
STINNETT, JA
MADIX, RJ
机构
[1] STANFORD UNIV,DEPT CHEM ENGN,STANFORD,CA 94305
[2] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND
基金
美国国家科学基金会;
关键词
D O I
10.1016/0039-6028(93)90214-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The adsorption probability of xenon on Pt(110)(1 x 2) shows a strong dependence on both the polar (theta(i)) and aximuthal angles of incidence. For atoms incident along the (110BAR) direction the adsorption probability increases slowly with increasing angle of incidence, scaling as E(i) cos0.5theta, whereas along the (100) azimuth it decreases with increasing angle of incidence, exhibiting ''negative'' energy scaling. The hard cube washboard model does not account quantitatively for these differences with a single consistent set of parameters.
引用
收藏
页码:L148 / L155
页数:8
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