SOLUBILITY OF HYDROGEN-CHLORIDE IN ZINC-CHLORIDE PLUS SODIUM-CHLORIDE MELTS

被引：5

作者：

HAMILTON, HG ^{[1
]}

INMAN, D ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT MAT,LONDON SW7 2AZ,ENGLAND

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1992年 / 37卷 / 04期

关键词：

D O I：

10.1021/je00008a018

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Measurement of the solubility of HCI gas in ZnCl2 + NaCl binary molten mixtures has been carried out by an elution technique. The solubility data were found to exhibit trends characteristic of a chemical dissolution process, implying the formation of a complex species. It is suggested that as the melt basicity is increased the predominant species changes from a coordinated zinc species to HCl2-, with the more basic melts tending toward behavior exhibited by HCI in pure molten alkali-metal chlorides.

引用

页码：456 / 458

页数：3

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