LIGAND AND METAL EFFECTS ON THE REACTIVITY OF METAL-CARBONYLS

被引：12
|
作者：
ATWOOD, JD
机构：
[1] Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 383卷 / 1-3期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0022-328X(90)85122-F
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactivity of metal carbonyl complexes is surveyed. The effect of charge, electron count, row and electronic configuration of the metal are examined for mononuclear carbonyls and more limited information is examined for metal clusters. Ligand effects are also examined for the metal carbonyls. The reactivity of metal carbonyl complexes changes by at least 15 orders of magnitude. This paper provides a framework for understanding such a range of reactivity. © 1990.
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页码：59 / 69
页数：11
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