INVESTIGATION OF A NOVEL AQUEOUS ALUMINUM SULFUR BATTERY

被引：42
|
作者：
PERAMUNAGE, D
DILLON, R
LICHT, S
机构：
[1] Department of Chemistry, Clark University, Worcester
来源：
JOURNAL OF POWER SOURCES | 1993年 / 45卷 / 03期
关键词：
D O I：
10.1016/0378-7753(93)80020-P
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electrolytic and electrodic effects are investigated for a novel aluminum/sulfur battery based on concentrated polysulfide catholytes and an alkaline aluminum anode. The battery is expressed by aluminum oxidation and aqueous sulfur reduction for an overall battery discharge consisting of: 2Al+S(4)2-+2OH-+4H2O-->2Al(OH)3+4HS- E(cell)=1.79V The theoretical specific energy of the Al/S battery (based on potassium salts) is 647 Wh kg-1. A first generation aluminum/sulfur battery is demonstrated with an open-circuit voltage of 1.3 V, and a specific energy of 110 Wh kg-1.
引用
收藏
页码：311 / 323
页数：13
相关论文
共 50 条
  • [1] A novel non-aqueous aluminum sulfur battery
    Cohn, Gil
    Ma, Lin
    Archer, Lynden A.
    JOURNAL OF POWER SOURCES, 2015, 283 : 416 - 422
  • [2] A NOVEL AQUEOUS ALUMINUM FERRICYANIDE BATTERY
    LICHT, S
    MARSH, C
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (12) : L109 - L111
  • [3] NOVEL AQUEOUS ALUMINUM SULFUR BATTERIES
    LICHT, S
    PERAMUNAGE, D
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (01) : L4 - L6
  • [4] Investigation of a sodium hypochlorite catholyte for an aluminum aqueous battery system
    Medeiros, MG
    Zoski, CG
    JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (49): : 9908 - 9914
  • [5] A NOVEL AQUEOUS DUAL-CHANNEL ALUMINUM HYDROGEN-PEROXIDE BATTERY
    MARSH, C
    LICHT, S
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (06) : L61 - L63
  • [6] The low current domain of the aluminum/sulfur battery
    Licht, S
    Hwang, J
    Light, TS
    Dillon, R
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (03) : 948 - 955
  • [7] Aqueous cerium ion battery: A novel aqueous rechargeable battery
    Zheng, Jia
    Liu, Jiaxin
    Zhang, Ruiying
    Zhi, Xiaodong
    Chen, Qiong
    Feng, Zhongmin
    Sun, Ting
    JOURNAL OF POWER SOURCES, 2024, 616
  • [8] A rechargeable aqueous aluminum-sulfur battery through acid activation in water-in-salt electrolyte
    Hu, Zhiqiu
    Guo, Yue
    Jin, Hongchang
    Ji, Hengxing
    Wan, Li-Jun
    CHEMICAL COMMUNICATIONS, 2020, 56 (13) : 2023 - 2026
  • [9] Aluminum/sulfur battery discharge in the high current domain
    Licht, S
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) : L133 - L136
  • [10] An Aluminum-Sulfur Battery with a Fast Kinetic Response
    Yang, Huicong
    Yin, Lichang
    Liang, Ji
    Sun, Zhenhua
    Wang, Yuzuo
    Li, Hucheng
    He, Kuang
    Ma, Lipo
    Peng, Zhangquan
    Qiu, Siyao
    Sun, Chenghua
    Cheng, Hui-Ming
    Li, Feng
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (07) : 1898 - 1902
12345