INFLUENCE OF GAMMA-IRRADIATION ON EXTRACTION AND CATION-TRANSPORT OF URANIUM(VI) AND PLUTONIUM(IV) BY DICYCLOHEXANO-18-CROWN-6

被引:12
|
作者
SHUKLA, JP [1 ]
KUMAR, A [1 ]
SINGH, RK [1 ]
机构
[1] BHABHA ATOM RES CTR, POWER REACTOR FUEL REPROCESSING PLANT, BOMBAY 400085, INDIA
关键词
PLUTONIUM NITRATES; URANIUM NITRATES; EXTRACTION; PLUTONIUM IONS; URANIUM IONS; CROWN ETHER; PERMEATION; CATION TRANSPORT; GAMMA-RADIATION; RADIATION DAMAGE; RADIATION DOSES; DOSE DEPENDENCE; DC18C6;
D O I
10.3327/jnst.31.1066
中图分类号
TL [原子能技术]; O571 [原子核物理学];
学科分类号
0827 ; 082701 ;
摘要
Changes of the extraction behaviour and cation-transport of U(VI) and Pu(IV) nitrates with gamma-irradiated DC18C6 in toluene have been investigated. The effect of radiation damage to DC18C6 for extraction and permeation at excessively higher doses (70 Mrads) has been studied systematically. No deterioration in its performance is noted at lower doses. Hydrolytic stability of the macrocycle/diluent system in the presence of nitric acid and radiolytic stability of immobilized liquid membrane using 'Enka' Accurel flat sheet polypropylene membrane films as solid support are also examined.
引用
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页码:1066 / 1072
页数:7
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