ORGANOMETALLIC OXIDES - LACUNARY LINDQVIST-TYPE POLYANION-SUPPORTED CYCLOPENTADIENYLRHODIUM COMPLEX FRAGMENTS

被引：22

作者：

PROUST, A ^{[1
]}

GOUZERH, P ^{[1
]}

ROBERT, F ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM METAUX TRANSIT LAB,CNRS,URA 419,4 PL JUSSIEU,F-75252 PARIS 05,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 01期

关键词：

D O I：

10.1002/anie.199301151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A role as tetradentate bridging(~)ligand is. given to [Mo5O13-(OMe)4(NO)]3-, a lacunary Lindqvist-type polyanion, on synthesis of the novel polyoxomolybdate-supported cyclopentadienyl rhodium complex 1. The rhodium atoms achieve an 18-electron configuration with two terminal axial oxygen atoms, a Cp* ring, and one bromide ligand. [GRAPHICS]

引用

页码：115 / 116

页数：2

共 26 条

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