KINETIC-STUDIES OF THIOLANE SYNTHESIS FROM TETRAHYDROFURANE AND H2S

被引：1

作者：

MASHKIN, VY

DESYATOV, IV

MASHKINA, AV

机构：

[1] Institute of Catalysis, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1992年 / 47卷 / 01期

关键词：

Chemisorption - Reaction kinetics - Synthesis (chemical);

D O I：

10.1007/BF02063569

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetic studies of tetrahydrofuran reaction with H2S were carried out in a flow-circulation reactor. Presumably, the reaction takes place through dissociative chemisorption of reactants and the interaction of surface structures formed to produce thiolane and water. A kinetic equation that agrees with the suggested mechanism has been derived.

引用

页码：119 / 123

页数：5

共 6 条

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DESYATOV, IV ;

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MASHKINA, AV .

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[2] MECHANISM OF CATALYTIC HYDRODEOXYGENATION OF TETRAHYDROFURAN [J].

FURIMSKY, E .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1983, 22 (01) :31-34

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GURYANOVA EN, 1973, DONOR ACCEPTOR BONDS

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[5]

Mashkina A. V., 1977, HETEROGENEOUS CATALY

[6]

TEMKIN MI, 1957, ZH FIZ KHIM+, V31, P3

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