Crystal structure of 1-phenylimido-1-{6-[1-(phenylimino)ethyl]pyridin-2-yl}ethan-1-yl-kappa N-3,N ',N '')- iron(II)

被引：1
|
作者：
Lau, Ka-Cheong [1 ]
Filatov, Alexander S. [1 ]
Jordan, Richard F. [1 ]
机构：
[1] Univ Chicago, Dept Chem, 5735 South Ellis ave, Chicago, IL 60637 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷
关键词：
crystal structure; bis(imino)pyridine ligand; pyridine-diimine; redox-active; iron; radical anion;
D O I：
10.1107/S2056989016015528
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title iron complex, [Fe(C21H19N3)(2)], consists of an Fe-II atom chelated by two tridentate bis(imino)pyridine radical anions in a slightly distorted octahedral coordination environment. In the solid state, there are two independent half molecules in the asymmetric unit, and the complete molecular structure is formed by applying twofold rotation symmetry with the twofold rotation axis passing through an Fe atom. In the crystal, the Fe-containing complexes are not involved in any particular direct intermolecular interactions, with the shortest C-H-Ar contacts between neighboring phenyl groups being ca 3.2 angstrom.
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收藏
页码：1595 / +
页数：13
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