STEREOSELECTIVE ALKYLATION OF METHYL (2-TRIBUTYLSTANNYL)TETRAHYDROFURAN-3-YLCARBOXYLATE LITHIUM ENOLATE - ACCESS TO 2,3,3-TRISUBSTITUTED TETRAHYDROFURANS

被引：9

作者：

ZHAO, YK ^{[1
]}

BEDDOES, RL ^{[1
]}

QUAYLE, P ^{[1
]}

机构：

[1] VICTORIA UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)73147-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stereoselective synthesis of 2,3,3 -trifunctionalised tetrahydrofurans is described.

引用

页码：4187 / 4188

页数：2

共 50 条

[41] Synthesis of clavulones (claviridenones) via [3+2] annulation using reaction of (beta-(phenylthio)acryloyl)silane with lithium enolate of alkyl methyl ketone [J].

Takeda, K ;

Nakajima, A ;

Yoshii, E .

SYNLETT, 1997, (03) :255-&

[42] Deacylative alkylation (DaA) of N-methyl-3-acetyl-2-oxindole for the synthesis of symmetrically 3,3-disubstituted 2-oxindoles. An access gate to anticancer agents and natural products [J].

Moreno-Cabrerizo, Cristina ;

Ortega-Martinez, Aitor ;

Molina, Cynthia ;

Najera, Carmen ;

Sansano, Jose M. .

ANAIS DA ACADEMIA BRASILEIRA DE CIENCIAS, 2018, 90 :1089-1099

[43] DFT and ONIOM study on the alkylation of the lithium enolate in solution: microsolvation cluster models for CH2=CHOLi + CH3Cl + (THF)0-6 [J].

Ando, Kaori ;

Morokuma, Keiji .

THEORETICAL CHEMISTRY ACCOUNTS, 2011, 130 (2-3) :323-331

[44] Lithium trialkoxo[tris(trimethylsilyl)methyl]aluminates, analogues of intermediates in reductions of carbonyl compounds.: Crystal structures of [Li(thf)2][AlR(OEt)3] and {Li[AlR(OPri)2(OH)]}2, R = C(SiMe3)3 and thf = tetrahydrofuran [J].

Chen, WY ;

Eaborn, C ;

Gorrell, IB ;

Hitchcock, PB ;

Hopman, M ;

Smith, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (24) :4689-4693

[45] 3-Aryl-5-vinyl-2-isoxazolines and 3-aryl-5-vinylisoxazoles from aryl nitrile oxides and methyl vinyl ketone lithium enolate: Reaction limits and synthetic utility exploitation [J].

Salomone, Antonio ;

Scilimati, Antonio ;

Vitale, Paola .

Synthesis (Germany), 2015, 47 (06) :807-816

[46] 3-Aryl-5-vinyl-2-isoxazolines and 3-Aryl-5-vinylisoxazoles from Aryl Nitrile Oxides and Methyl Vinyl Ketone Lithium Enolate: Reaction Limits and Synthetic Utility Exploitation [J].

Salomone, Antonio ;

Scilimati, Antonio ;

Vitale, Paola .

SYNTHESIS-STUTTGART, 2015, 47 (06) :807-816

[47] Lithium trialkoxo[tris(trimethylsilyl)-methyl]aluminates, analogues of intermediates in reductions of carbonyl compounds. Crystal structures of [Li(thf)2][AlR(OEt)3] and {Li[AlR(OPr1)2(OH)]}2, R - C(SiMe3)3 and thf = tetrahydrofuran [J].

Chen, W.-Y. ;

Eaborn, C. ;

Gorrell, I. B. ;

Hitchcock, P. B. .

Journal of the Chemical Society.Dalton Transactions, (24)

[48] A convenient stereoselective access to novel 1,2,4-triazepan-3-ones/thiones via reduction or reductive alkylation of 7-membered cyclic semicarbazones and thiosemicarbazones [J].

Fesenko, Anastasia A. ;

Grigoriev, Mikhail S. ;

Shutalev, Anatoly D. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 16 (43) :8072-8089

[49] Efficient synthesis of (R)-6-benzyloxycarbonylamino-1-methyl-4(3-methyl-benzyl)hexahydro-1,4-diazepine.: 2.: Novel formation of hexahydro-1,4-diazepine ring using 1,2,3-trisubstituted aminopropane derivative and glyoxal [J].

Harada, H ;

Morie, T ;

Suzuki, T ;

Yoshida, T ;

Kato, S .

TETRAHEDRON, 1998, 54 (36) :10671-10676

[50] Highly efficient and stereoselective access to (Z)-α,β-difluoroallyl alcohols and (Z)-α-fluoro-α,β-unsaturated aldehydes based on the reaction of 2,3,3-trifluoro-1-propenyl p-chlorobenzenesulfonate with Grignard reagents [J].

Funabiki, K ;

Fukushima, Y ;

Inagaki, T ;

Murata, E ;

Matsui, M ;

Shibata, K .

TETRAHEDRON LETTERS, 1998, 39 (14) :1913-1916

← 1 2 3 4 5 →