COMPLETE ASSIGNMENT OF THE H-1 AND C-13 NMR-SPECTRA OF A PENTACYCLO [5.4.0.0(2,6).0(3,10).0(5,9)]UNDECANE DERIVATIVE

被引：21

作者：

CADD, DH ^{[1
]}

FEAST, WJ ^{[1
]}

KENWRIGHT, AM ^{[1
]}

SAY, JM ^{[1
]}

机构：

[1] UNIV DURHAM,INTERDISCIPLINARY RES CTR POLYMER SCI & TECHNOL,SOUTH RD,DURHAM DH1 3LE,ENGLAND

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1993年 / 31卷 / 09期

关键词：

H-1; NMR; C-13; TRICYCLIC UNDECANE DERIVATIVES; PENTACYCLIC UNDECANE DERIVATIVES;

D O I：

10.1002/mrc.1260310903

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The production of compounds derived from intramolecular photocycloaddition reactions upon Diels-Alder adducts has received considerable attention, but assignment of the NMR spectra of the photoaddition products has proved problematic, rendering structural determination difficult. This paper reports the complete assignments of the proton and carbon NMR spectra of 11,11-dimethoxypentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecan-8-one and the assignment of the spectra of pentacyclo [5.4.0.0(2,6).0(3,10).0(5,9)]undecan-8,11-dione by analogy.

引用

页码：801 / 807

页数：7

共 29 条

[1]

Albrecht W, 1906, LIEBIGS ANN CHEM, V348, P31

[2] 2-DIMENSIONAL SPECTROSCOPY - APPLICATION TO NUCLEAR MAGNETIC-RESONANCE [J].

AUE, WP ;

BARTHOLDI, E ;

ERNST, RR .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (05) :2229-2246

[3] AN NMR TECHNIQUE FOR TRACING OUT THE CARBON SKELETON OF AN ORGANIC-MOLECULE [J].

BAX, A ;

FREEMAN, R ;

FRENKIEL, TA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (08) :2102-2104

[4] INVESTIGATION OF COMPLEX NETWORKS OF SPIN-SPIN COUPLING BY TWO-DIMENSIONAL NMR [J].

BAX, A ;

FREEMAN, R .

JOURNAL OF MAGNETIC RESONANCE, 1981, 44 (03) :542-561

[5]

CADD DH, 1992, THESIS U DURHAM

[6] PHOTOCHEMICAL CYCLISATION OF DIELS-ALDER ADDUCTS [J].

COOKSON, RC ;

CRUNDWELL, E ;

HILL, RR ;

HUDEC, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (SEP) :3062-&

[7] BARRIERS TO INTRAMOLECULAR HYDRIDE TRANSFERS IN SOME POLYCYCLIC HYDROXYKETONES [J].

CRAZE, GA ;

WATT, I .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1981, (01) :175-184

[8]

DAVIS TL, 1943, CHEM POWDERS EXPLOSI, P192

[9] CAGE COMPOUNDS .4. H-1 AND C-13 NMR-STUDY OF 3,6-EPOXYPENTACYCLO-[6.2.2.02,7.04,10.05,9]DODECANE AND 3,6-EPOXYPENTACYCLO-[6.2.1.02,7.04,10.05,9]UNDECANE [J].

DEKKER, TG ;

PACHLER, KGR ;

WESSELS, PL ;

DEKKER, J ;

DEKKER, JJ ;

FOURIE, L .

ORGANIC MAGNETIC RESONANCE, 1978, 11 (10) :520-523

[10] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

← 1 2 3 →