ELECTROCHEMICAL OXIDATION OF ALPHA,BETA-UNSATURATED KETONES

被引：1

作者：

TAKAHASHI, T ^{[1
]}

NAKAGAWA, T ^{[1
]}

SAKAI, N ^{[1
]}

SONO, M ^{[1
]}

SHIZURI, Y ^{[1
]}

机构：

[1] UNIV TOKUSHIMA, FAC PHARMACEUT SCI, YAMASHIRO CHO, TOKUSHIMA 770, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 01期

关键词：

D O I：

10.1246/cl.1993.177

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alpha,beta-Unsaturated ketones were successfully oxidized by using electrochemical method. In this oxidation reaction, allylic methyl or methylene groups were converted into acetoxylmethyl group or methoxy carbonyl group. In contrast, these unsaturated ketones were stable to Sharpless's method (a combination of selenium dioxide and (t)butyl hydroperoxide).

引用

页码：177 / 180

页数：4

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