ENDOR STUDIES ON THE INTERACTION OF METHANOL WITH COPPER(II) DITHIOPHOSPHATE COMPLEX

被引:2
作者
YORDANOV, ND
ZDRAVKOVA, M
机构
[1] Institute of Kinetics and Catalysis, Bulgarian Academy of Sciences
关键词
D O I
10.1016/0167-7322(92)80052-J
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The interaction between methanol and bis(O,O'-di-iso-propyl-dithiophosphato)copper(II) complex is studied by the method of H-1 ENDOR spectroscopy. It is found that hydroxylic proton of methanol is coordinated approximately in axial and equatorial position. The distances and polar angles of its towards the copper complex coordinate system are estimated.
引用
收藏
页码:103 / 110
页数:8
相关论文
共 16 条
[11]  
YORDANOV ND, 1984, 22 P C AMPERE ZUR, P612
[12]  
YORDANOV ND, 1971, INORG CHIM ACTA, V6, P679
[13]  
YORDANOV ND, 1982, INORG CHIM ACTA, V60, P19
[14]  
YORDANOV ND, 1990, IN PRESS COMPT REND
[15]  
YORDANOV ND, 1988, COORDINATION CHEM CA, P461
[16]  
1960, INORGANIC SYNTHESIS, V6, P142