CONDITIONS FOR THE FORMATION OF SUPERCONDUCTIVE POLYMERS AND POSSIBILITIES FOR THEIR REALIZATION

被引：19
作者：
GRIGOROV, LN
机构：
来源：
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1990年 / 37卷
关键词：
D O I：
10.1002/masy.19900370115
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
General principles of the creation of superconductivity at the polymers are considered. It is shown that high temperature superconductivity may be produced only at really one‐dimensional conducting materials. It is also shown that conjugated polymers cannot have onedimensional conductivity. The new class of nonconjugated polar elastomers is proposed as a perspective one for the creation of high temperature superconductive structures–superpolarons–which appear as a result of internal selfionization of the polymer matrix and a consequent selforganization of free polarons. The practical methods of the formation of superpolarons are shown for the films of oxidized atactice polypropylene. Evidences are given which show the existence of superconductive structures in oxidized polypropylene at room temperature. Copyright © 1990 Hüthig & Wepf Verlag
引用
收藏
页码：159 / 176
页数：18
相关论文
共 12 条
[1]  
Grigorov L.N., Smirnova S.G., (1988)
[2]  
Little W.A., Possibility of Synthesizing an Organic Superconductor, Physical Review, 134, 6 A, (1964)
[3]  
Kivelson S., Zimanyi G.T., Mol. Cryst. Liq. Cryst., 160, (1988)
[4]  
Andrejev V.M., Grigorov L.N., Vysokomol. Soedin., Ser. B, 30, 12, (1988)
[5]  
Grigorov L.N., Andrejev V.M., Smirnova S.G.
[6]  
Grigorov L.N., Andrejev V.M., Vysokomol. Soedin., Ser. B, 30, 8, (1988)
[7]  
Enikolopyan N.S., Gruzdeva S.G., Galashina N.M., Shklyarova E.I., Grigorov L.N., Dokl. Akad. Nauk SSSR, Ser. Fiz. Khim., 283, 6, (1985)
[8]  
Smirnova S.G., Demicheva O.V., Grigorov L.N., Pis'ma Zh. Eksp. Teor. Fiz., 48, 4, (1988)
[9]  
Smirnova S.G., Grigorov L.N., Demicheva O.V., Vysokomol. Soedin., Ser. B, 31, 5, (1989)
[10]  
Enikolopyan N.S., Grigorov L.N., Smirnova S.G., Pis'ma Zh. Eksp. Teor. Fiz., 49, 6, (1989)
12