REACTIONS AND SYNTHESES WITH ORGANOMETALLIC COMPOUNDS .6. NEW SYNTHESIS OF INDOLE, QUINOLINE, AND BENZAZEPINE DERIVATIVES VIA ARYLNICKEL COMPLEXES

被引:31
作者
MORI, M [1 ]
KUDO, S [1 ]
BAN, Y [1 ]
机构
[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 03期
关键词
D O I
10.1039/p19790000771
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
o-Chloroaniline derivatives with an internal double bond were treated with MeMgBr (200 mol %) in the presence of a catalytic amount of NiCl 2(PPh3)2 (1 mol %) to furnish heterocyclic compounds such as indole, quinoline, and even benzazepine derivatives in good yield.
引用
收藏
页码:771 / 774
页数:4
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