ELECTRONIC-ENERGY TRANSFER ACROSS ETHYNYL-BRIDGED RU-II/OS-II TERPYRIDYL COMPLEXES

被引：186

作者：

GROSSHENNY, V

HARRIMAN, A

ZIESSEL, R

机构：

[1] UNIV TEXAS,CTR FAST KINET RES,AUSTIN,TX 78712

[2] ECOLE EUROPEENNE HAUT ETUD IND CHIM STRASBOURG,CHIM ELECTR & PHOTON MOLEC LAB,IPCMS,URM 46,F-67008 STRASBOURG,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 10期

关键词：

ELECTRONIC ENERGY TRANSFER; OSMIUM COMPOUNDS; PHOTOCHEMISTRY; RUTHENIUM COMPOUNDS;

D O I：

10.1002/anie.199511001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate of intramolecular triplet energy transfer upon excitation of the RuII unit in the binuclear complex 1 decreases by roughly a third when the alkyne spacer is extended by a second ethynyl group (complex 2). The metal—metal distance increases by 2.4 Å, and correspondingly the attenuation factor for electron exchange through the CC bonds is 0.17 Å−1. Counterion PF 6−. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：1100 / 1102

页数：3

相关论文

共 29 条

[1] VERTICAL AND NONVERTICAL ENERGY-TRANSFER PROCESSES - A GENERAL CLASSICAL TREATMENT [J].

BALZANI, V ;

BOLLETTA, F ;

SCANDOLA, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (07) :2152-2163

[2]

BALZANI V, 1991, SUPRAMOLECULAR PHOTO

[3] RIGID ROD-LIKE DINUCLEAR RU(II) OS(II) TERPYRIDINE-TYPE COMPLEXES - ELECTROCHEMICAL-BEHAVIOR, ABSORPTION-SPECTRA, LUMINESCENCE PROPERTIES, AND ELECTRONIC-ENERGY TRANSFER THROUGH PHENYLENE BRIDGES [J].

BARIGELLETTI, F ;

FLAMIGNI, L ;

BALZANI, V ;

COLLIN, JP ;

SAUVAGE, JP ;

SOUR, A ;

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) :7692-7699

[4] LUMINESCENCE PROPERTIES OF RIGID ROD-LIKE BINUCLEAR RUTHENIUM(II)-OSMIUM(II) TERPYRIDINE COMPLEXES - ELECTRONIC INTERACTION THROUGH PHENYL BRIDGES [J].

BARIGELLETTI, F ;

FLAMIGNI, L ;

BALZANI, V ;

COLLIN, JP ;

SAUVAGE, JP ;

SOUR, A ;

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (11) :942-944

[5]

Benniston A. C., 1994, ANGEW CHEM, V33, P1884

[6] ELECTRON DELOCALIZATION IN POLYENE-BRIDGED BINUCLEAR COMPLEXES [J].

BENNISTON, AC ;

GOULLE, V ;

HARRIMAN, A ;

LEHN, JM ;

MARCZINKE, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (32) :7798-7804

[7]

BENNISTON AC, 1994, ANGEW CHEM INT EDIT, V33, P1884, DOI 10.1002/anie.199418841

[8] PROTEIN ELECTRON-TRANSFER RATES SET BY THE BRIDGING SECONDARY AND TERTIARY STRUCTURE [J].

BERATAN, DN ;

BETTS, JN ;

ONUCHIC, JN .

SCIENCE, 1991, 252 (5010) :1285-1288

[9] EFFECT ON MLCT EXCITED-STATES OF ELECTRONIC DELOCALIZATION IN THE ACCEPTOR LIGAND [J].

BOYDE, S ;

STROUSE, GF ;

JONES, WE ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (20) :7395-7396

[10] DYNAMICS OF ELECTRON-TRANSFER BETWEEN INTERCALATED POLYCYCLIC MOLECULES - EFFECT OF INTERSPERSED BASES [J].

BRUN, AM ;

HARRIMAN, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (10) :3656-3660