(DTEDT)[AU(CN)(2)](0.4) - AN ORGANIC SUPERCONDUCTOR BASED ON THE NOVEL PI-ELECTRON FRAMEWORK OF VINYLOGOUS BIS-FUSED TETRATHIAFULVALENE

被引：132

作者：

MISAKI, Y

HIGUCHI, N

FUJIWARA, H

YAMABE, T

MORI, T

MORI, H

TANAKA, S

机构：

[1] TOKYO INST TECHNOL,FAC ENGN,DEPT ORGAN & POLYMER MAT,TOKYO 152,JAPAN

[2] INT SUPERCONDUCT TECHNOL CTR,TOKYO 135,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期

关键词：

ORGANIC CONDUCTORS; SUPERCONDUCTORS; TETRATHIAFULVALENES;

D O I：

10.1002/anie.199512221

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Below 4 K the [Au(CN)2] salt of the radical cation of 1 shows superconductivity. The X‐ray structure analysis reveals that this salt has a two‐dimensional array of donors. The relatively large interactions between the stacks result in a closed Fermi surface. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1222 / 1225

页数：4

相关论文

共 26 条

[1] VINYLOGS OF TETRATHIAFULVALENE (TTF) BEARING 4 1,4-DITHIAFULVEN-6-YL SUBSTITUENTS - NOVEL HIGHLY EXTENDED AND SULFUR-RICH PI-DONORS [J].

BELYASMINE, A ;

FRERE, P ;

GORGUES, A ;

JUBAULT, M ;

DUGUAY, G ;

HUDHOMME, P .

TETRAHEDRON LETTERS, 1993, 34 (25) :4005-4008

[2] 2,5-BIS(1,4-DITHIAFULVEN-6-YL) FURANS, THIOPHENES AND N-METHYL PYRROLES AS EXTENDED ANALOGS OF TETRATHIAFULVALENE [J].

BENAHMEDGASMI, AS ;

FRERE, P ;

GARRIGUES, B ;

GORGUES, A ;

JUBAULT, M ;

CARLIER, R ;

TEXIER, F .

TETRAHEDRON LETTERS, 1992, 33 (43) :6457-6460

[3] NEW EXTENDED PI-ELECTRON DONORS - TETRATHIAFULVALENE SYSTEMS WITH HETEROCYCLIC SPACER GROUPS [J].

HANSEN, TK ;

LAKSHMIKANTHAM, MV ;

CAVA, MP ;

NIZIURSKIMANN, RE ;

JENSEN, F ;

BECHER, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :5035-5039

[4] SYNTHESIS AND PROPERTIES OF NEW PI-DONOR SULFUR HETEROCYCLES [J].

HANSEN, TK ;

LAKSHMIKANTHAM, MV ;

CAVA, MP ;

METZGER, RM ;

BECHER, J .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (08) :2720-2722

[5]

Ishiguro T., 1990, ORGANIC SUPERCONDUCT

[6]

KAWAUCHI S, UNPUB

[7]

KHODORKOVSKII VY, 1990, KHIM GETEROTSIKL+, P130

[8] STRUCTURE AND CONDUCTING PROPERTIES OF BDT-TTP SALTS [J].

MISAKI, Y ;

FUJIWARA, H ;

YAMABE, T ;

MORI, T ;

MORI, H ;

TANAKA, S .

CHEMISTRY LETTERS, 1994, (09) :1653-1656

[9] METHYLTHIO SUBSTITUTED 2,5-BIS(1',3'-DITHIOL-2'-YLIDENE)-1,3,4,6-TETRATHIAPENTALENE - A BIS-FUSED TETRATHIAFULVALENE [J].

MISAKI, Y ;

NISHIKAWA, H ;

KAWAKAMI, K ;

KOYANAGI, S ;

YAMABE, T ;

SHIRO, M .

CHEMISTRY LETTERS, 1992, (12) :2321-2324

[10] PREPARATION, CRYSTAL-STRUCTURE AND ELECTRICAL-PROPERTIES OF DIMETHYL SUBSTITUTED UNSYMMETRICAL 2,5-BIS(1',3'-DITHIOL-2'-YLIDENE)-1,3,4,6-TETRATHIAPENTALENES [J].

MISAKI, Y ;

KAWAKAMI, K ;

MATSUI, T ;

YAMABE, T ;

SHIRO, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) :459-460