SYNTHESIS AND STRUCTURE OF A NEW BIS[(TRIMETHYLPHOSPHANE)TITANOCENE] COMPLEX WITH A BRIDGING C-2 UNIT

被引：44
作者：
BINGER, P
MULLER, P
PHILIPPS, P
GABOR, B
MYNOTT, R
HERRMANN, AT
LANGHAUSER, F
KRUGER, C
机构：
来源：
CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 10期
关键词：
TITANOCENE COMPLEXES; CYCLOPROPANE; METHYLENE; COMPLEXES; BIS(TITANOCENYL)ACETYLENE COMPLEX;
D O I：
10.1002/cber.19921251007
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bis(trimethylphosphane)titanocene (1) reacts with 2-methyl-1,1-diphenylcyclopropane (2) to give red crystalline (eta2-2-methylene-1,1-diphenylcyclopropane)(trimethylphosphane)titanocene (3). In solution complex 3 degrades smoothly to form the new Cp2Ti(PMe3) - C2 - Ti(PMe3)Cp2 complex 4, the crystal structure of which has been elucidated by an X-ray analysis.
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页码：2209 / 2212
页数：4
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