REACTION OF TRICHLOROMETHYL AND TRICHLOROMETHYLPEROXYL RADICALS WITH C-60 - A PULSE-RADIOLYSIS STUDY

被引：41

作者：

DIMITRIJEVIC, NM

机构：

[1] Radiation Laboratory, University of Notre Dame, Notre Dame

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 194卷 / 4-6期

关键词：

D O I：

10.1016/0009-2614(92)86082-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Both trichloromethyl (.CCl3) and trichloromethylperoxyl (CCl3OO.) radicals react with C60. The bimolecular rate constants are (2.7+/-0.5)x10(8) mol-1 dm3 s-1 and 2x10(6) mol-1 dm3 s-1, respectively. The transient absorption spectra of the radical adducts are presented.

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页码：457 / 460

页数：4

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