STRUCTURE, CONFORMATION AND REACTIVITY OF ORGANOTRANSITION METAL PI-COMPLEXES .2. X-RAY CRYSTALLOGRAPHIC CHARACTERIZATION OF 2 NEUTRAL HALF-SANDWICH CR(CO)3 COMPLEXES

被引：7

作者：

ZAWOROTKO, MJ ^{[1
]}

ATWOOD, JL ^{[1
]}

PRIESTER, RD ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,UNIVERSITY,AL 35487

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1990年 / 22卷 / 03期

关键词：

CHROMIUM; CARBONYL; ARENE; CONFORMATION; X-RAY STRUCTURE;

D O I：

10.1080/00958979009408217

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preferred solid state conformations adopted by two (É6-ligand)Cr(CO)3 (É6-ligand: mesitylene, I; N-phenyl-2, 5-dimethylpyrrole, 2) complexes have been determined via single crystal X-ray crystallographic methods. I adopts a conformation such that the C6 ring carbon atoms are eclipsed with respect to the carbonyl ligands. Such a conformation is predictable from both steric and electronic considerations. 2, however, adopts a staggered conformation that must be attributed to the steric requirements of the bulky 2, 5-dimethylpyrrole substituent. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：209 / 217

页数：9

共 50 条

[41] Mass-spectroscopy of polynuclear palladium carboxylate complexes as a key to new structures. Synthesis and X-Ray structure of Pd12(μ-CO)8(μ-NO2)8(μ-iPrCO2)8
Shishilov, Oleg N.
Churakov, Andrei V.
Kuz'mina, Lyudmila G.
Akhmadullina, Nailya S.
Efimenko, Inessa A.
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (10) : 1685 - 1689
[42] Ternary complexes metal [Co(II), Ni(II), Cu(II) and Zn(II)]-ortho-iodohippurate (I-hip)-acyclovir.: X-ray characterization of isostructural [(Co, Ni or Zn)(I-hip)2(ACV)(H2O)3] with stacking as a recognition factor
Barceló-Oliver, M
Terrón, A
García-Raso, A
Fiol, JJ
Molins, E
Miravitlles, C
JOURNAL OF INORGANIC BIOCHEMISTRY, 2004, 98 (11) : 1703 - 1711
[43] X-ray crystal structures of [Et3NH][{(CO)5Mo(P(OCH2CMe2CH2O)O)}2H] and (CO)5Mo{μ-Ph2POPPh2}Mo(CO)5, two complexes derived from the hydrolysis of coordinated chloro-phosphorous-donor ligands
Owens, Samuel B., Jr.
Kaisare, Abha A.
Gray, Gary M.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2007, 37 (10) : 655 - 661
[44] Osmium-carbonyl complexes of naphthylazoimidazoles.: Single crystal X-ray structure of [Os(H)(CO)(PPh3)2(α-NaiEt)](PF6) {α-NaiEt=1-ethyl-2-(naphthyl-α-azo)imidazole}
Mondal, T. K.
Dinda, Joydev
Slawin, Alexandra M. Z.
Woollins, J. Derek
Sinha, C.
POLYHEDRON, 2007, 26 (03) : 600 - 606
[45] Palladium(I) and palladium(II) unsaturated carboxylate complexes with small molecules: Synthesis and X-ray structure of Pd4(μ-CO)4(μ-trans-CH3CH=CHCO2)4 and Pd4(μ-NO)2(μ-CH2=C(CH3)CO2)6
Shishilov, Oleg N.
Ankudinova, Polina V.
Nikitenko, Elena V.
Churakov, Andrei V.
Garbuzova, Irina A.
Akhmadullina, Nailya S.
Minaeva, Natalia A.
Demina, Lyudmila I.
Efimenko, Inessa A.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 767 : 112 - 119
[46] Improved synthesis of di- and trinuclear iron carbonyl complexes containing bridging diphenylethenyl ligand.: X-ray structure of [PPh4][Fe2(CO)6(μ-CO)(μ-PhC=CHPh)]
Elarraoui, A
Ros, J
Mathieu, R
Yáñez, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 678 (1-2) : 117 - 121
[47] X-ray Crystal Structures of [Et3NH][{(CO)5Mo(P(OCH2CMe2CH2O)O)}2H] and (CO)5Mo{μ-Ph2POPPh2}Mo(CO)5, Two Complexes Derived from the Hydrolysis of Coordinated Chloro-Phosphorous-Donor Ligands
Samuel B. Owens
Abha A. Kaisare
Gary M. Gray
Journal of Chemical Crystallography, 2007, 37 : 655 - 661
[48] SYNTHESIS AND X-RAY STRUCTURE OF THE DIVALENT AND TRIVALENT YTTERBIUM-MOLYBDENUM COMPLEXES YB(II)(HMPA)4(MU-OCMO(CO)2CP)2 AND [YB(III)(HMPA)5(MU-OCMO(CO)2CP)][CPMO(CO)3]2-CENTER-DOT-THF
HOU, ZM
AIDA, K
TAKAGI, Y
WAKATSUKI, Y
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 473 (1-2) : 101 - 104
[49] Synthesis, Characterization, and X-ray Crystallography, of the First Cyclohexadienyl Trifluoromethyl Metal Complex (η5-C6H7)Fe(CO)2CF3
Douvris, Chris
Matatov, David
Bussan, Derek
Lampropoulos, Christos
Wink, Donald J.
MOLECULES, 2022, 27 (21):
[50] Nickel(II) and copper(II) complexes of 5-(4-methoxy-phenyl) [1,3,4]-oxadiazole-2-thione: Synthesis and X-ray characterization
Singh, N. K.
Kushawaha, S. K.
Bharty, M. K.
Dulare, Ram
Butcher, R. J.
JOURNAL OF MOLECULAR STRUCTURE, 2009, 936 (1-3) : 257 - 263

← 1 2 3 4 5 →