A MOLYBDENUM-PHOSPHORUS TRIPLE BOND - SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE TERMINAL PHOSPHIDO (P3-) COMPLEX [MO(P)NRAR)(3)]

被引：140

作者：

LAPLAZA, CE ^{[1
]}

DAVIS, WM ^{[1
]}

CUMMINS, CC ^{[1
]}

机构：

[1] MIT,DEPT CHEM 2227,CAMBRIDGE,MA 02139

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 18期

关键词：

COMPLEXES WITH PHOSPHIDO LIGANDS; MOLYBDENUM COMPOUNDS; MULTIPLE BONDS; PHOSPHORUS COMPOUNDS;

D O I：

10.1002/anie.199520421

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molybdenum complex 1 and white phosphorus react smoothly at 28°C to give 2 with a terminal phosphido (P3−) ligand. The crystal structure of 2 reveals a monomer with a Mo–P triple bond (2.119(4) Å). Treatment of 2 with mesityl azide gives a complex with a terminal iminophosphenium (PNR+) ligand; treatment with elemental sulfur leads to a phosphorus monosulfide (PS) complex, R = C(CD3)2CH3, Ar = 3,5‐C6H3Me2. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：2042 / 2044

页数：3

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