DETERMINATION OF PORE-SIZE AND PORE-SIZE DISTRIBUTION .1. ADSORBENTS AND CATALYSTS

被引:544
作者
KANEKO, K
机构
[1] Department of Chemistry, Faculty of Science, Chiba University, Inage, Chiba, 263
关键词
PORE SIZE; PORE SIZE DISTRIBUTION; MICROPORE; PHYSICAL ADSORPTION; MICROPORE FIELD; SMALL ANGLE X-RAY SCATTERING; SURFACE CHARACTERIZATION;
D O I
10.1016/0376-7388(94)00126-X
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Various kinds of pores in solid materials are classified into intraparticle pores and interparticle pores according to the origin of the pores. The structural factors of the pores are discussed as well as the methods for evaluation of the pore size distribution with molecular adsorption (molecular resolution porosimetry), small angle X-ray scattering, mercury porosimetry, nuclear magnetic resonance, and thermoporositmetry. Recent progresses in molecular resolution porosimetry for micropores are stressed; this review describes new approaches such as high resolution N2 adsorption, He adsorption at 4.2 K, and molecular simulation for the characterization of porous solids.
引用
收藏
页码:59 / 89
页数:31
相关论文
共 116 条
[11]  
BARRER RM, 1978, ZEOLITES CLAY MINERA, pCH2
[12]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[13]   PHYSISORPTION OF NITROGEN AND OXYGEN BY MCM-41, A MODEL MESOPOROUS ADSORBENT [J].
BRANTON, PJ ;
HALL, PG ;
SING, KSW .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (16) :1257-1258
[14]  
Broekhoff J. C. P., 1970, PHYSICAL CHEM ASPECT, P23
[15]  
BROEKHOFF JCP, 1970, PHYSICAL CHEM ASPECT, P4
[16]  
BROEKHOFF JCP, 1970, PHYSICAL CHEM ASPECT, pCH1
[17]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[18]   ADSORPTION HYSTERESIS IN POROUS MATERIALS [J].
BURGESS, CGV ;
EVERETT, DH ;
NUTTALL, S .
PURE AND APPLIED CHEMISTRY, 1989, 61 (11) :1845-1852
[19]  
Carrott P. J. M., 1988, P IUPAC S COPS I, P77
[20]   MEASUREMENT OF THE MORPHOLOGY OF HIGH SURFACE-AREA SOLIDS - HYSTERESIS IN MERCURY POROSIMETRY [J].
CONNER, WC ;
LANE, AM ;
HOFFMAN, AJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1984, 100 (01) :185-193