THE ABSOLUTE-CONFIGURATION OF DECILONITROSE, A SUGAR COMPONENT OF DECILORUBICIN, IS UNDOUBTEDLY 2,3,6-TRIDEOXY-3-C-METHYL-3-NITRO-L-RIBO-HEXOPYRANOSE

被引：16

作者：

NISHIMURA, Y

ISHII, K

机构：

[1] Institute of Microbial Chemistry, Shinagawa-ku, Tokyo 141

来源：

JOURNAL OF ANTIBIOTICS | 1990年 / 43卷 / 01期

关键词：

D O I：

10.7164/antibiotics.43.54

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The absolute structure of decilonitrose, a sugar component of an antitumor antibiotic decilorubicin was decided to be 2,3,6-trideoxy-3-C-methyl-3-nitro-L-ribo-hexopyranose by synthesis of its methyl β-glycoside starting from L-rhamnose through the 3-ulose. In the synthetic route, any configurational ambiguities do not exist. © 1990, JAPAN ANTIBIOTICS RESEARCH ASSOCIATION. All rights reserved.

引用

页码：54 / 61

页数：8

共 13 条

[1] STRUCTURE OF PACHYBIOSE AND ASCLEPOBIOSE . DESOXY SUGARS .44. [J].