REACTION OF (ETA-5-C13H9)MN(CO)3 WITH ALKYLPHOSPHINES - FORMATION AND ISOLATION OF ETA-1-FLUORENYL COMPLEXES

被引：34

作者：

BIAGIONI, RN ^{[1
]}

LORKOVIC, IM ^{[1
]}

SKELTON, J ^{[1
]}

HARTUNG, JB ^{[1
]}

机构：

[1] GRINNELL COLL,DEPT CHEM,GRINNELL,IA 50112

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 03期

关键词：

D O I：

10.1021/om00117a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of (η5-C13H9)Mn(CO)3 with L = PEt3 or PBu3 leads to formation of (η1-C13H9Mn(CO)3L2. The L = PEt3 complex was isolated analytically pure in moderate yield and characterized as the trans-meridional isomer by1H,31P, and13C NMR and IR spectroscopies. (η1-C13H9)Mn(CO)3L2 decomposes via Mn-C bond homolysis to the C13H9 radical and Mn(CO)3L2, which reacts further to yield HMn(CO)3L2. (η1-C13H9)Mn(CO)3L2 can also be prepared by reacting L with (η6-C13H9)Mn(CO)3, apparently via a novel η6 to η1 shift. © 1990, American Chemical Society. All rights reserved.

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页码：547 / 551

页数：5

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