Crystal structure of trans-1,4-bis[(trimethylsilyl)oxy]cyclohexa-2,5-diene-1,4-dicarbonitrile

被引：4

作者：

Gloecklhofer, Florian ^{[1
]}

Froehlich, Johannes ^{[1
]}

Stoeger, Berthold ^{[2
]}

Weil, Matthias ^{[2
]}

机构：

[1] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria

[2] Vienna Univ Technol, Inst Chem Technol & Analyt, Div Struct Chem, Getreidemarkt 9-164-SC, A-1060 Vienna, Austria

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2014年 / 70卷

关键词：

Cyanohydrin; cyclohexa-2,5-diene; crystal structure;

D O I：

10.1107/S1600536814014251

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, C14H22N2O2Si2, contains one half of the molecule, which is completed by inversion symmetry. The cyclohexa-2,5diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) angstrom] and two pairs of single bonds [1.5121 (13) and 1.5073 (14) angstrom]. The tetrahedral angle between the sp(3)-C atom and the two neighbouring sp(2)-C atoms in the cyclohexa-2,5-diene ring is enlarged by about 3 degrees.

引用

页码：77 / +

页数：6

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