HYBRIDIZATION OF ROTOR STATES IN PARALLEL ELECTRIC AND MAGNETIC-FIELDS

被引：26

作者：

FRIEDRICH, B ^{[1
]}

SLENCZKA, A ^{[1
]}

HERSCHBACH, D ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST PHYS & THEORET CHEM,D-93053 REGENSBURG,GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 221卷 / 5-6期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(94)00362-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We demonstrate in a spectroscopic experiment the hybridization of rotor states within the X and A electronic states of ICl, induced by parallel magnetic and electric fields of up to 0.7 T and 50 kV /cm. For a polar paramagnetic electronic state, such as the A state, the electric and magnetic fields conjoin in producing hybridization for one half of the molecular ensemble while they counteract for the other half. In the latter case the electric and magnetic effects can be tuned to balance out exactly; the concomitant field-induced hyperfine splitting remains in place, however, despite the resulting free rotation of the molecule.

引用

页码：333 / 340

页数：8

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