STRUCTURE OF N-(2-PHENYLETHENYL)PYRROLIDIN-2-ONE

被引:1
|
作者
WOYDT, M
RADEMACHER, P
NIEGER, M
机构
[1] UNIV ESSEN GESAMTHSCH,INST ORGAN CHEM,UNIV STR 5-7,POSTFACH 103764,W-4300 ESSEN 1,GERMANY
[2] UNIV BONN,INST ANORGAN CHEM,W-5300 BONN,GERMANY
关键词
D O I
10.1107/S0108270191006728
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
C12H13NO, M(r) = 187.2, orthorhombic, Pbca, a = 10.896(3), b = 8.033 (2), c = 23.376 (8) angstrom, V = 2046 (1) angstrom 3, Z = 8, D(x) = 1.216 Mg m-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 0.072 mm1, F(000) = 800, room temperature, final R = 0.058 for 1290 observed reflections. The ethylene group of the title compound has a trans configuration and is antiperiplanar to the amide system of the lactam ring. The five-membered lactam ring is nearly planar with a mean deviation of 0.005 angstrom from the plane. The crystal structure is stabilized by weak intermolecular H...O interactions between the vinylic beta-H atom and the carbonyl O atom of the next molecule, with a distance of 2.59 angstrom.
引用
收藏
页码:101 / 103
页数:3
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