REMOVAL OF RESIDUAL MONOMERS FROM POLYMER EMULSIONS BY STEAM STRIPPING

被引:4
作者
MEHOS, G [1 ]
QUICK, D [1 ]
机构
[1] CORNELL UNIV,DEPT CHEM ENGN,ITHACA,NY 14853
关键词
D O I
10.1080/01496399408002176
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Removal rates of residual monomers from polymer emulsions by batch steam stripping were modeled. Model parameters were emulsion batch charge, steam sparge rate, emulsion solids content, and phase-equilibrium relationships for systems containing monomer, polymer, and water. Experiments in which steam was sparged into a column partially filled with emulsion were performed to verify the model. The model and data showed good agreement. Theory and experiments demonstrated that monomer desorption was dependent upon steam sparge rate and solids content, whereas temperatures had little effect on monomer removal.
引用
收藏
页码:1841 / 1856
页数:16
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