REMOVAL OF RESIDUAL MONOMERS FROM POLYMER EMULSIONS BY STEAM STRIPPING

被引:4
作者
MEHOS, G [1 ]
QUICK, D [1 ]
机构
[1] CORNELL UNIV,DEPT CHEM ENGN,ITHACA,NY 14853
关键词
D O I
10.1080/01496399408002176
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Removal rates of residual monomers from polymer emulsions by batch steam stripping were modeled. Model parameters were emulsion batch charge, steam sparge rate, emulsion solids content, and phase-equilibrium relationships for systems containing monomer, polymer, and water. Experiments in which steam was sparged into a column partially filled with emulsion were performed to verify the model. The model and data showed good agreement. Theory and experiments demonstrated that monomer desorption was dependent upon steam sparge rate and solids content, whereas temperatures had little effect on monomer removal.
引用
收藏
页码:1841 / 1856
页数:16
相关论文
共 50 条
[21]   DETERMINATION OF POLYDEXTROSE (POLYMER) AND RESIDUAL MONOMERS IN POLYDEXTROSE BY LIQUID-CHROMATOGRAPHY [J].
THOMAS, JW ;
BROWN, DL ;
HOCH, DJ ;
LEARY, JJ ;
DOKLADALOVA, J .
JOURNAL OF THE ASSOCIATION OF OFFICIAL ANALYTICAL CHEMISTS, 1991, 74 (03) :571-573
[22]   Numerical Simulation of a Steam Injector for Passive Residual Heat Removal [J].
Schulenberg, Thomas ;
Heinze, David .
JOURNAL OF NUCLEAR ENGINEERING AND RADIATION SCIENCE, 2020, 6 (03)
[23]   STEAM STRIPPING AND BATCH DISTILLATION FOR THE REMOVAL AND OR RECOVERY OF VOLATILE ORGANIC-COMPOUNDS FROM INDUSTRIAL-WASTES [J].
HASSAN, SQ ;
TIMBERLAKE, DL .
JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION, 1992, 42 (07) :936-943
[24]   STEAM STRIPPING FOR REMOVAL OF ORGANIC POLLUTANTS FROM WATER .2. VAPOR-LIQUID-EQUILIBRIUM DATA [J].
HWANG, YL ;
OLSON, JD ;
KELLER, GE .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1992, 31 (07) :1759-1768
[25]   DETERMINATION OF RESIDUAL MONOMER IN POLYMER EMULSIONS BY RAPID DISTILLATION AND GAS CHROMATOGRAPHY [J].
TWEET, O ;
MILLER, WK .
ANALYTICAL CHEMISTRY, 1963, 35 (07) :852-&
[26]   Purification of polymers from solvents by steam or gas stripping [J].
Quadri, G.P. .
Industrial and Engineering Chemistry Research, 1998, 37 (07) :2850-2863
[27]   Purification of polymers from solvents by steam or gas stripping [J].
Quadri, GP .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (07) :2850-2863
[28]   Design of steam-stripping columns for removal of volatile organic compounds from water using random and structured packings [J].
Ortiz-Del Castillo, JR ;
Guerrero-Medina, G ;
Lopez-Toledo, J ;
Rocha, JA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (03) :731-739
[29]   Generation mechanism of residual direct current voltage for liquid crystal cells with polymer layers produced from monomers [J].
Mizusaki, Masanobu ;
Enomoto, Satoshi ;
Hara, Yuki .
LIQUID CRYSTALS, 2017, 44 (04) :609-617
[30]   PROCESS FOR REMOVING RESIDUAL MONOMERS FROM SYNTHETIC LATEXES [J].
BOLOTNIK.FS ;
BELENKII, LB .
ZHURNAL PRIKLADNOI KHIMII, 1972, 45 (05) :1049-+