A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL1(2)](ClO4)(2) (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

被引：15

作者：

Shepherd, Helena J. ^{[1
]}

Tonge, George ^{[1
]}

Hatcher, Lauren E. ^{[2
]}

Bryant, Mathew J. ^{[2
]}

Knichal, Jane V. ^{[2
]}

Raithby, Paul R. ^{[2
]}

Halcrow, Malcolm A. ^{[3
]}

Kulmaczewski, Rafal ^{[3
]}

Gagnon, Kevin J. ^{[4
]}

Teat, Simon J. ^{[4
]}

机构：

[1] Univ Kent, Sch Phys Sci, Canterbury CT2 7NH, Kent, England

[2] Univ Bath, Dept Chem, Claverton Down, Bath BA2 7AY, Avon, England

[3] Univ Leeds, Sch Chem, Woodhouse Lane, Leeds LS2 9JT, W Yorkshire, England

[4] Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA

来源：

MAGNETOCHEMISTRY | 2016年 / 2卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

spin-crossover; molecular materials; high pressure; order-disorder phenomena;

D O I：

10.3390/magnetochemistry2010009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL1(2)](ClO4)(2) (L1 = 2,6-bisI3-methylpyrazol-1-yll-pyrazine) and the concomitant anion order-disorder transition.

引用

页数：9

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