THE REACTIONS OF XENON DIFLUORIDE WITH INERT SOLVENTS

被引：33

作者：

DUKAT, WW

HOLLOWAY, JH

HOPE, EG

TOWNSON, PJ

POWELL, RL

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

[2] ICI PLC,CHEM & POLYMERS,RUNCORN,CHESHIRE,ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 62卷 / 2-3期

关键词：

D O I：

10.1016/S0022-1139(00)80103-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of XeF2 with a variety of organic solvents are described. XeF2 is found to undergo both hydrogen- and chlorine-fluorine exchange over a relatively short timescale with chloroform, dichloromethane and dibromomethane. XeF2 reacts very slowly with tetrachloromethane and fluorotrichloromethane, although the addition of a catalytic amount of HF increases the rate of reaction considerably. XeF2 dissolves in acetonitrile with negligible reaction to the extent of 2.25 mol kg-1.

引用

页码：293 / 296

页数：4

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