CATALYTIC EPOXIDATION OF OLEFINS BY DIOXYGEN IN THE PRESENCE OF TRANSITION-METAL COMPLEXES AND A COREDUCER

被引：0

作者：

ATLAMSANI, A ^{[1
]}

PEDRAZA, E ^{[1
]}

POTVIN, C ^{[1
]}

DUPREY, E ^{[1
]}

MOHAMMEDI, O ^{[1
]}

BREGEAULT, JM ^{[1
]}

机构：

[1] CNRS,URA 1106,REACT SURFACES LAB,F-75005 PARIS,FRANCE

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II | 1993年 / 317卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

In the presence of dioxygen (P = 0.1 MPa) at room temperature (or at 40-degrees-C), epoxides and Me2CHCO2H are prepared by cooxidation of trans-2-octene [or of 1-octene, (R)-(+)-limonene, etc.] and Me2CHCHO in the presence of a soluble catalyst (ruthenium, rhodium, palladium, titanium, samarium complexes, etc.) or of a solid catalyst (Pd/HZ zeolite, TiO2, titanium silicalite, KTiOPO4, etc.).

引用

页码：757 / 762

页数：6

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