OBSERVATION OF ULTRAVIOLET SPECTRA OF SATURATED BICYCLIC AMINES

被引：9

作者：

MCKINNEY, TM

机构：

[1] Department of Chemistry University of California, Riverside

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 02期

关键词：

D O I：

10.1016/0584-8539(69)80045-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The ultraviolet spectra of triethylenediamine (I), 2-methyl triethylenediamine (II), and quinuclidine (III) have been observed. In each case, the vapor of the compound shows a rich pattern of vibrational structure of the electronic transition. This phenomenon is explained in terms of the rigidity of the molecules. © 1969.

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页码：501 / &

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共 11 条

[1] ACID BASE STUDIES IN GASEOUS SYSTEM .5. DISSOCIATION OF THE ADDITION COMPOUND OF TRIMETHYLBORON WITH QUINUCLIDINE - FURTHER EVIDENCE FOR THE STERIC CONFIGURATION OF TRIETHYLAMINE [J].

BROWN, HC ;

SUJISHI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (09) :2878-2881

[2] X-RAY AND INFRA-RED STUDIES OF BICYCLO(2.2.2)OCTANE TRIETHYLENEDIAMINE AND QUINUCLIDINE .3. ASSIGNMENTS OF HIGH AND LOW TEMPERATURE INFRA-RED SPECTRA . COMPARISON WITH X-RAY RESULTS [J].

BRUESCH, P ;

GUNTHARD, HH .

SPECTROCHIMICA ACTA, 1966, 22 (05) :877-&

[3] EXCITED STATES OF BENZENE .2. ANALYSIS OF THE 1ST ULTRAVIOLET BAND SYSTEM OF THE ABSORPTION SPECTRUM OF BENZENE [J].

GARFORTH, FM ;

INGOLD, CK .

JOURNAL OF THE CHEMICAL SOCIETY, 1948, (APR) :417-427

[4]

GRAHAM WH, 1962, J AM CHEM SOC, V84, P1064

[5] BENZYNES DEHYDROCONJUGATED MOLECULES AND INTERACTION OF ORBITALS SEPARATED BY A NUMBER OF INTERVENING SIGMA BONDS [J].

HOFFMANN, R ;

IMAMURA, A ;

HEHRE, WJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (06) :1499-&

[6] TRIETHYLENEDIAMINE CATION RADICAL [J].

MCKINNEY, TM ;

GESKE, DH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (13) :3013-&

[7]

MEISENHEIMER J, 1920, ANN, V420, P190

[8] ROTATIONAL ANALYSIS OF THE NEAR ULTRAVIOLET ABSORPTION SPECTRUM OF PYRAZINE [J].

MERRITT, JA ;

INNES, KK .

SPECTROCHIMICA ACTA, 1960, 16 (08) :945-&

[9] THE FAR ULTRAVIOLET ABSORPTION SPECTRA OF SIMPLE ALKYL AMINES [J].

TANNENBAUM, E ;

COFFIN, EM ;

HARRISON, AJ .

JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (02) :311-318

[10] CRYSTAL STRUCTURE AND THERMODYNAMICAL INVESTIGATIONS OF TRIETHYLENEDIAMINE, C6H12N2 [J].

WADA, T ;

KISHIDA, E ;

TOMIIE, Y ;

SUGA, H ;

SEKI, S ;

NITTA, I .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1960, 33 (09) :1317-1318