REACTION OF [OS4(MU-CL)(CO)13]- WITH THE [AU(PPH3)]+ CATION INVOLVING INSERTION OF AN OS(CO)4 FRAGMENT INTO THE GOLD PHOSPHORUS BOND

被引：12

作者：

CATHEY, C ^{[1
]}

LEWIS, J ^{[1
]}

RAITHBY, PR ^{[1
]}

DE ARELLANO, MCR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE, CHEM LAB, LENSFIELD RD, CAMBRIDGE CB2 1EW, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 22期

关键词：

D O I：

10.1039/dt9940003331

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the cluster anion [Os4(mu-Cl)(CO)13]- 1 with [Au(PPh3)]+ affords the cluster [OS3{mu-AuOs(CO)4(PPh3)}(mu-Cl)(CO)10] 2 which represents the first example in which an Os(CO)4 fragment has been inserted in to a gold-phosphine bond; the structure of 2 has been established by a single-crystal X-ray analysis.

引用

页码：3331 / 3332

页数：2

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