PROPERTIES AND SWELLING CHARACTERISTICS OF CROSS-LINKED POLY(VINYL ALCOHOL) CHITOSAN BLEND MEMBRANE

被引：177

作者：

KIM, JH ^{[1
]}

KIM, JY ^{[1
]}

LEE, YM ^{[1
]}

KIM, KY ^{[1
]}

机构：

[1] HANYANG UNIV,COLL ENGN,DEPT IND CHEM,SEOUL 133791,SOUTH KOREA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1992年 / 45卷 / 10期

关键词：

D O I：

10.1002/app.1992.070451004

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Blend membrane consisting of poly (vinyl alcohol) (PVA) and chitosan was prepared from a solvent-casting technique and characterized for their intermolecular interactions using infrared and X-ray diffraction methods. Cross-linking the blend with glutaraldehyde produces a membrane with lower crystallinity and a smaller swelling degree, but having improved thermostability and mechanical properties. The present blend membrane shows a pH-dependent swelling characteristic and will be discussed in detail.

引用

页码：1711 / 1717

页数：7

共 10 条

[1]

Finch C.A., 1981, CHEM TECHNOLOGY WATE, P90

[2]

KIM JH, IN PRESS

[3] MECHANICAL-PROPERTIES OF POLYVINYL-ALCOHOL CHITOSAN BLEND FILMS [J].

MIYA, M ;

YOSHIKAWA, S ;

IWAMOTO, R ;

MIMA, S .

KOBUNSHI RONBUNSHU, 1983, 40 (10) :645-651

[4] FT-IR STUDY OF INTERMOLECULAR INTERACTIONS IN POLYMER BLENDS [J].

MIYA, M ;

IWAMOTO, R ;

MIMA, S .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1984, 22 (06) :1149-1151

[5]

MUZZARELLI RAA, 1979, CHITIN, P82

[6]

MUZZARELLI RAA, 1979, CHITIN, P103

[7] CELLULOSE POLYVINYL-ALCOHOL) BLENDS PREPARED FROM SOLUTIONS IN N,N-DIMETHYLACETAMIDE LITHIUM-CHLORIDE [J].

NISHIO, Y ;

MANLEY, RS .

MACROMOLECULES, 1988, 21 (05) :1270-1277

[8] SOLUTE DIFFUSION IN SWOLLEN MEMBRANES .2. INFLUENCE OF CROSSLINKING ON DIFFUSIVE PROPERTIES [J].

REINHART, CT ;

PEPPAS, NA .

JOURNAL OF MEMBRANE SCIENCE, 1984, 18 (MAR) :227-239

[9]

SAKURAI K, 1984, SEN-I GAKKAISHI, V40, P55

[10] STUDIES OF SYNTHESIS AND PERMEABILITIES OF SPECIAL POLYMER MEMBRANES .51. ACTIVE-TRANSPORT OF HALOGEN IONS THROUGH CHITOSAN MEMBRANES [J].

URAGAMI, T ;

YOSHIDA, F ;

SUGIHARA, M .

JOURNAL OF APPLIED POLYMER SCIENCE, 1983, 28 (04) :1361-1370

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