STUDY OF THE REACTIVITY OF CYANAMIDE VIS-A-VIS O-EPOXIDE AND N-EPOXIDE GROUPS

被引：2
作者：
GRENIERLOUSTALOT, MF
BENTE, MP
GRENIER, P
机构：
[1] Laboratoire de chimie organique physique, CNRS URA 474-GDR 966, Helioparc, Pau-Pyrénées, 2, rue du president Angot
来源：
EUROPEAN POLYMER JOURNAL | 1992年 / 28卷 / 08期
关键词：
D O I：
10.1016/0014-3057(92)90330-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The aim of this work is to elucidate effect of the stoichiometric ratio and the temperature on the curing mechanism of the cyanamide epoxide system. Monofunctional model compounds (N,N methyl glycidyl aniline and phenyl glycidyl ether) were used to study the reaction products. The products were analysed using HPLC, C-13-NMR. FTIR and DSC. The results show that various reaction pathways (rearrangement, addition, ring opening) are simultaneous; the structures of products are proposed.
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页码：987 / 1000
页数：14
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