THE STEREOCHEMISTRY OF ORGANOMETALLIC COMPOUNDS .36. RHODIUM-CATALYZED REACTIONS OF UNSATURATED AMINES WITH HYDROGEN AND CARBON-MONOXIDE - A NEW SYNTHESIS OF 2-PIPERIDINONES

被引：16
|
作者：
ANASTASIOU, D
JACKSON, WR
机构：
[1] Department of Chemistry, Monash University, Clayton
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期
关键词：
D O I：
10.1016/0022-328X(91)80065-R
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rhodium-catalysed reactions of 5-aminopent-1-enes with carbon monoxide and hydrogen give 2-piperidinone derivatives in high yields under mild conditions. Reaction of allylamine under similar conditions gave exclusively 2-pyrrolidone in high yield and reactions of 4-aminobut-1-enes gave mixtures of 2-piperidinones and 2-pyrrolidinones. The role of the hydrogen in these reactions is discussed.
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页码：399 / 410
页数：12
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