BRIDGE OPENING SELECTIVITY IN THE ADAMS-COTTON MECHANISM - PREPARATION AND FLUXIONAL BEHAVIOR OF (ETA-5-CP)2FE2(CO)2(CNBU-T)2

被引：16

作者：

HOWELL, JAS

MATHUR, P

机构：

[1] Department of Chemistry, University of Keele, Keele,

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)85598-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title molecule exists in solution as a mixture of (η5-Cp)2Fe2(μ-CO)2(CNBu-t)2 and (η5-Cp)2Fe2(μ-CO)(μ-CNBu-t)(CO)(CNBu-t) isomers. NMR studies show that interconversion by the Adams-Cotton mechanism proceeds by two different pathways having significantly different activation energies. © 1979.

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页码：335 / 341

页数：7

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